Should electrochemists care about VSF spectroscopy?

Short answer, yes. If you’re still not convinced see Yujin’s invited reference module, In-Situ Probing of Adsorbates at Electrochemical Interfaces with Vibrational Sum Frequency Spectroscopy, just accepted for publication in the Enclyclopedia of Interfacial Chemistry: Surface Science and Electrochemistry ( e-mail for preprint).